![]() Even so, HF is safer and easier to transport and handle than pure fluorine. Hydrofluoric acid (HF), for example, is so corrosive it will dissolve glass. Because it is so reactive, fluorine is difficult to store.While fluorine compounds are not found in animals, there are natural organofluorines in plants, which typically act as defenses against herbivores. Trace dietary fluorine levels may impact bone strength. ![]() Topical fluoride application, as from toothpaste or mouthwash, was once believed to be effective for the conversion of tooth enamel hydroxyapatite into stronger fluorapatite, but more recent studies indicate fluoride aids enamel regrowth. Fluorine is not an essential element in human or animal nutrition. It is used in refrigerants (chlorofluorocarbons or CFCs), propellants, and for the enrichment of uranium by UF 6 gas. It is found as fluoride in toothpaste and drinking water, in Teflon (polytetrafluoroethylene), drugs including the chemotherapeutic drug 5-fluorouracil, and etchant hydrofluoric acid. The element is found in minerals, including fluorite, topaz, and feldspar. It is so reactive that it is not found naturally in pure form but only in compounds. The 13th most abundant element in the Earth's crust is fluorine.Moisson was also the first person to make artificial diamonds, by compressing charcoal. He also used electrolysis to obtain the element but kept the fluorine gas separate from the hydrogen gas. Although he was the first to successfully obtain pure fluorine, Moisson's work was interrupted multiple times when he was poisoned by the reactive element. George Gore managed to isolate fluorine using an electrolytic process in 1869, but the experiment ended in disaster when fluorine reacted explosively with hydrogen gas. Henri Moisson was awarded the 1906 Nobel Memorial Prize in Chemistry for isolating fluorine in 1886. ![]() ![]() Its standard atomic weight is 18.9984 and is based on its single natural isotope, fluorine-19.
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![]() ![]() Lightweight and compact, with the 170 HP of the new V4 Granturismo, the fourth generation Multistrada will give you a sporty and exhilarating ride on the turns. The first important maintenance interval will be only after 37,300 miles. ![]() Ready for long journeys thanks to the navigator that can be viewed on the dashboard and the innovative riding assistance radar system, the new Multistrada V4 will offer you excellent riding comfort. Once and half the world’s circumference of fun.After your adventures you will feel great ease and control in daily use thanks to the advanced electronic ride assist systems and the ability to adjust the seat down to 810 mm in height. Ready for long journeys thanks to the navigation-system that can be viewed on the dashboard and the innovative rider assistance radar-system, it will offer you excellent riding comfort and a main service-interval only after 36,000 miles, the Oil Service, are now scheduled at 9,300 miles or 24 months.Īnd when the asphalt ends fun will continue thanks to the high ground clearance, the electronic suspension, the surprisingly fluid power delivery and the perfect ergonomics for stand-up riding. Lightweight and compact, with the new 170 HP V4 Granturismo engine for a sporty and exciting ride on mixed terrain. ![]() Sportier and more touring, stronger in off-road use and easier in urban action. Get ready to discover the fourth Multistrada generation. 2023 Ducati Multistrada V4S Iceberg White - Forged Wheels ![]() ![]() ![]() AudioMass Audio Editing Software Audio Mass Online Audio Editing SoftwareĪudioMass is a versatile, free, and open-source web-based audio editor designed for music producers, musicians, and creators. Advanced users might find some limitations in comparison to professional-grade softwareĢ.May require additional downloads for certain functions (e.g., LAME encoder library for exporting MP3 files).Free Audio Recording To Record Voiceovers.Record multiple channels simultaneously.Record at sample rates up to 192,000 Hz.Built-in effects like Distortion, Echo, Limiter, Paulstretch, Phaser, Reverb, and Reverse.Plug-in Manager for easy installation and management of effects and generators.High-quality resampling and dithering for sample rates and format conversion.Export MP3 files with the optional LAME encoder library.Easy editing with Cut, Copy, Paste, and Delete functions.Supports 16-bit, 24-bit, and 32-bit audio.Import and export multiple file formats, including WAV, AIFF, AU, FLAC, and Ogg Vorbis.Record live audio through a microphone or mixer.The software also provides unlimited sequential Undo and Redo steps, so you can experiment and tweak your project without the fear of making irreversible changes.Īudacity also features a wide selection of built-in effects, such as Distortion, Echo, Limiter, Paulstretch, Phaser, Reverb, and Reverse, adding depth and character to your audio creations. You can also export your recordings in various formats, including multiple files at once.įor more advanced users, Audacity supports a range of plugins, including LADSPA, LV2, Nyquist, VST, and Audio Unit effect plug-ins, allowing you to customize and expand the software’s capabilities.Įditing audio files is simple with Audacity’s intuitive Cut, Copy, Paste, and Delete functions. ![]() The software supports multiple file formats, including WAV, AIFF, AU, FLAC, and Ogg Vorbis, making it easy to import, edit, and combine sound files. ![]() Record live audio through a microphone or mixer, or digitize recordings from other media. Audacity Audacity | Free Audio Editing SoftwareĪudacity is a versatile and user-friendly audio editor program that caters to the needs of producers, musicians, podcasters, content creators, and anyone looking to create or edit files.Īudacity is free, open-source software that runs seamlessly on Windows, macOS, and Linux.Īudacity offers a comprehensive suite of features that make audio editing a breeze, even for beginners. Best Audio Editor Software Programs Best Free Audio Editor Software ProgramsĬlick the buttons below to visit each website’s audio editor. ![]() ![]() ![]() PKGNAME: makemkv Flavors: there is no flavor information for this port. NOTE: If this package has multiple flavors (see below), then use one of them instead of the name specified above. ![]() To install the port: cd /usr/ports/multimedia/makemkv/ & make install clean To add the package, run one of these commands: There are no Conflicts Matches for this port. share/examples/makemkv/update-makemkv-key.sh./usr/local/share/licenses/makemkv-1.17.4/MAKEMKV./usr/local/share/licenses/makemkv-1.17.4/LICENSE./usr/local/share/licenses/makemkv-1.17.4/catalog.mk.¦ ¦ ¦ ¦ pkg-plist: as obtained via: make generate-plist Expand this list (22 items) Collapse this list. * Make sure you have the "linux" kernel module loaded. Kernel configuration and follow the instructions at To build such a kernel, add "device sg" to your * A custom FreeBSD kernel with sg devices (Linux' "scsi generic" interface) is Includes a small manpage to get you started using makemkvcon. Only the commandline interface works, so there is no GUI in this port. ![]() Most information but not changing it in any way. Proprietary (and usually encrypted) disc into a set of MKV files, preserving MakeMKV is a formatĬonverter, otherwise called "transcoder". Patents-unencumbered format that can be played everywhere. MakeMKV is your one-click solution to convert video that you own into free and Maintainer: Port Added: 15:10:33 Last Update: 17:19:33 Commit Hash: 82d860a People watching this port, also watch:: FreeCAD, virtualbox-ose, mpv, Cura, CuraEngine License: MAKEMKV LGPL21+ Description: Video converter reading from DVD and Bluray Makemkv Video converter reading from DVD and Blurayġ.17.4 multimedia =1 1.17.3 Version of this port present on the latest quarterly branch. Want a good read? Try FreeBSD Mastery: Jails (IT Mastery Book 15) All times are UTC FreshPorts - multimedia/makemkv: Video converter reading from DVD and BlurayĪs an Amazon Associate I earn from qualifying purchases. ![]() ![]() ![]() 6 In our baseline scenario (55% probability), we forecast GDP growth to slow to 0.9% in 2023 from an estimated 2% in 2022 and 5.9% in 2021. A slowing economy will keep retail sales growth in check.Three key economic trends will likely influence retail sales: 5 For an even deeper dive, download the full report.Ī note from Deloitte US Economists Danny Bachman and Akrur Barua To learn more about the emerging retail industry trends, explore them below. The results provide a unique outlook on how today's market, future expectations, and changing consumer needs inform strategies for the year ahead-and beyond. We wanted to better understand what traits separate leaders from the rest of the pack and to analyze planned strategies and investments for 2023. To check the pulse of retail executives, we asked 50 leaders about their expectations regarding challenges and opportunities in the upcoming year. They learned that rapidly evolving consumer preferences require more effective analytics and tools to build loyalty. Massive demand fluctuations during the pandemic forced retailers to rethink archaic systems in favor of more pliable operations. They’re also predicting hard times for consumers, with nearly all anticipating diminished consumption in 2023, resulting from rising financial concerns.īut the retail outlook is not all gloom and doom retailers have learned much about resiliency in the past few years. 1 Almost all retail executives expect inflation to pressure their profit margins. As we head into the new year, only one-third of retail executives are very confident about maintaining or improving profit margins in what are expected to be turbulent times. Retailers today are feeling the hangover of such volatility occurring in the most condensed time frame of any recent business cycle. Resiliency in bulk quantity: a retail industry overviewĬhange can be good, but constant change can be daunting. ![]() ![]() ![]() I love making chocolate bars for my family and. Mothers Day Candy Wrappers Availability: Usually ships in 1-5 business days after proof approval Minimum Purchase: 24 units 0.87 1.29 You save 0. □įor even more great ideas follow me on Facebook – Pinterest – Instagram – Twitter – Periscope. Just in time for (dutch) mothers day, but also perfect for an impromtu gift: these chocolate bar wrappers. ![]() □Ĭute and Simple and perfect for mom, right?!įor more great ideas for mom be sure to check out these easy projects:įor all Mother’s Day ideas on the site go HERE.Īnd get weekly emails with monthly freebies by signing up for the Lil’ Luna newsletter. Mother's Day Candy Wrappers Availability: Usually ships in 1-5 business days after proof approval Minimum Purchase: 24 units 0.87 1.29 You save 0.42 Fully Wrapped Candy Bars: Required No, wrappers & foil only - I will buy my own candy bars and wrap them myself. Chocolate Bar Boxes Tutorial Reese's Kit Kat 3Musketeers Hershey Snickers.Purchase some nice chocolate candy bars these wrappers fit 6.5 oz Hershey Candy Bars and other similarly sized candy bars. It’s no secret that most moms love chocolate. It’s usually a little trinket, flower or candy bar and personally I always prefer the candy bar!! LOL! In case you have to gather a cute wrapper for these candy bars I put together some spring-y type ones that would be perfect to use this weekend. How to Wrap Chocolate Bars with Foil + Printable Wrappers These Mother’s Day candy bar wrapper printables are so cute and the perfect way to pamper moms with some delicious chocolate. Add even more color by choosing colored text and/or colored foil. You can personalize your wrapper with photos, and text. These candy bar wrappers fit over a standard 1.55 oz. Choose from a variety of different styles and colors. I know some may be unfamiliar with this, but in the LDS church it’s typical for the men in the ward to give the women a little gift on Mother’s Day. Our line of Mother's Day Candy Wrappers are both elegant and fun. When I realized I didn’t I thought I’d whip up a few to use for those who would like to use them (especially those who are in charge of the candy bar treats for the moms at church). I don’t know why I hadn’t thought of making Mother’s Day Candy Bar Wrappers before, but a friend asked me this week if I had any on my site. ![]() ![]() ![]() Lincoln visited on the day before his death. Yates and Richard Oglesby were among the last persons with whom Mr. Maryland was originally a Catholic colony and several Yate sons from Lyford emigrated there. Then Kentucky, Tennessee, Illinois, and then into the western states’. Most of the Yates family genealogy was first through “Baltimore Maryland” into Virginia, where my family was from. We have been contacted by a descendant, now living in America, who notes that they are ‘a descendant of the Yate/Yates family into America in the 1600’s. So, ‘Frances’ and ‘Francis’ may indeed have been the same person. However, the spelling of Frances/Francis can occasionally be inconsistent for records of this period (at least when transcribed) and in the context of Yates I have come across the spelling ‘Frances’ being used for a male and ‘Francis’ for a female. If the widowed Frances Yate was still alive at the time, she was possibly the tenant of Charney Manor who sublet it. One of their daughters was Frances Clare Yate (1597?-1625), a Franciscan nun at Nieuport in Flanders. The first wife of this second Thomas was Mary Tregian, whose father was imprisoned for 28 years for harbouring the canonised Catholic martyr Cuthbert Mayne. Francis was the owner of Lyford and married Jane Tichborne (probably about 1560): their son, another Thomas Yate and also an owner of Lyford Grange, was born about 1570 and still alive in 1623. Thomas Yate (died 1565) married Frances White and they had a son called Francis (thought to be born in the early 1530s and who died in 1588). ![]() That said, the female form Frances is much rarer among the Yates. And there are John Yates and Mary Yates galore, often contemporaries living in close proximity. There were a number of Yate families in the Vale, so it is sometimes tricky to determine, for example, which Francis is which. With the Yates, as with so many families, we suffer from the problem of the same forenames being used not only in successive generations but also by cousins, etc. Tony Hadland has written to us and advised us of the following: In 1970 he was formally declared a saint by the Pope. It was there that Edward Campion was captured after a protracted search and he was eventually hanged, drawn and quartered. Lyford Grange at the time was a moated manor house similar in scale to Baddesley Clinton. John Yate owned sheep farms in Wantage and Lambourn in 1538 he bought the former Abingdon Abbey grange at nearby Lyford and moved there.’. His son John traded from there as a highly reputed merchant of the staple at Calais. In the mid-1400s, Richard Yate settled in Charney Bassett, a village a few miles south of Buckland. ‘The Yate family came to the Vale as wool merchants. ![]() ![]() ![]() Earth Defense Force 4.Dragon Quest Heroes II: Explorer's Edition.Dragon Quest Heroes: The World Tree's Woe and the Blight Below.Dragon Quest XI S: Echoes of an Elusive Age - Definitive Edition.Damascus Gear: Operation Tokyo HD Edition.Chocobo's Mystery Dungeon Every Buddy! - leaving.Sony Computer Entertainment / From Software / Japan Studio Balan Wonderworld (PS4 / PS5) - leaving.Alex Kidd in Miracle World DX (PS4 / PS5).Adventure Time Pirates of the Enchiridion. ![]() Cloud storageĪll PS Plus members, no matter the tier, get 100GB of cloud storage for game saves, so even if you lose your save data stored on a PS4 or PS5, you will be able to recover it later.Īlso, if you own a second console and want to carry on playing the same game, you can transfer save games from machine to machine. Traditionally, there are also added discounts for members on sale games during major sales periods. PS Plus members get exclusive discounts on many digital download games on the PlayStation Store. They are yours to keep as long as you remain a PS Plus member. Free gamesĮach month, two or three PS4/PS5 games are made available to download and play at no extra cost. Only some free-to-play games are exempt - the vast majority will only give you access to online multiplayer if you have an active PS Plus subscription. Online playĪ PlayStation Plus tier is a requirement for PS4 and PS5 gamers to play each other online. There are a number of benefits included with PS Plus membership. PS Plus Deluxe is cheaper than Premium - you should check your regional PlayStation Store for pricing, where applicable. PS Plus DeluxeĪn additional tier is available in markets that do not offer cloud gaming as an alternative to Premium. There are also time-limited trials in this tier. ![]() The highest tier, PS Plus Premium, incorporates all of the benefits of Essential and Extra, then adds up to 340 additional games on top, from the back catalogue of PS3, PS2, PSP and even original PlayStation games - often via cloud streaming. It includes all the benefits of the standard plan plus access to a catalogue of up to 400 PS4 and PS5 games to play at no extra cost. PS Plus Extra is now available in multiple locations (see region details above). Shame Alric is so op, the other free heroes arent as good but with some buffs they could be on his level. ![]() ![]() ![]() and that’s why I’m here,” Blanton told the television station from prison. “I think I was cleverly set up by the government. In a 2006 interview with Birmingham station WBRC-TV, he claimed the government used trumped-up evidence and lies to gain his conviction. “Tom Blanton saw change and didn’t like it,” Jones said in the trial.īlanton proclaimed his innocence years after being sent to prison. The targeted church was a rallying point for protesters. Attorney Jones, appointed as a special state prosecutor, said Blanton acted in response to months of civil rights demonstrations. Lisa McNair, the sister of Denise McNair, said she also hoped Blanton had repented and added: “I wish I could have sat down with him to find out if he had had a change of heart.”īlanton never admitted any role in the blast, but evidence showed he was part of a group of hard-core Klansmen who made a bomb and planted it on a Sunday morning.ĭuring the trial, then-U.S. "She hopes that he found Jesus Christ and repented,” George Rudolph said on behalf of his wife. The bodies of Denise McNair, 11, and Addie Mae Collins, Cynthia Wesley and Carole Robertson, all 14, were found in the downstairs lounge.Ĭollins’ sister, Sarah Collins Rudolph, survived the blast but lost her right eye and is known as the “fifth little girl.” Glass fragments remained in her chest, left eye and abdomen for decades after the explosion.Ī parole hearing was scheduled next year for Blanton, and Rudolph and her husband planned to attend in opposition to his release, which was denied during a previous hearing. 15, 1963, a bomb ripped through an exterior wall of the brick church, killing four girls who were inside preparing for a youth program. Cherry was convicted in 2002 and died in prison in 2004. Chambliss was convicted in 1977 and died in prison in 1985. The investigation into the bombing was stalled early and left dormant for long stretches, but two other ex-Klansmen, Robert Chambliss and Bobby Frank Cherry, also were convicted in the bombing in separate trials. Moderates could no longer remain silent and the fight to topple segregation laws gained new momentum. The church bombing, exposing the depths of hatred by white supremacists as Birmingham integrated its public schools, was a tipping point of the civil rights movement. “That he died at this moment, when the country is trying to reconcile the multi-generational failure to end systemic racism, seems fitting,” Jones said in a statement. Doug Jones, who prosecuted Blanton, said the fact that Blanton remained free for almost 40 years after the bombing “speaks to a broader systemic failure to hold him and his accomplices accountable.” When asked by the judge during sentencing if he had any comment, Blanton said: “I guess the good Lord will settle it on judgment day.” Ivey, in a statement, called the bombing “a dark day that will never be forgotten in both Alabama’s history and that of our nation.” In May 2001, Blanton was convicted of murder and sentenced to life in prison for the bombing of the 16th Street Baptist Church in Birmingham. He was being held at Donaldson prison near Birmingham, prison officials said. Kay Ivey’s office said Blanton died of natural causes. ![]() (AP) - Thomas Edwin Blanton Jr., the last of three one-time Ku Klux Klansmen convicted in a 1963 Alabama church bombing that killed four Black girls and was the deadliest single attack of the civil rights movement, died Friday in prison, officials said. ![]() ![]() This paved the way for more substantial production reactors at Hanford. It used highly purified graphite to slow the neutrons released in fission to enable further fission. During 1942, under conditions of wartime secrecy, the first human-designed reactor* had been constructed, in a squash court at the University of Chicago. The 21 kiloton explosive charge for the bomb detonated over Nagasaki three days later was provided by about 6.2 kilograms of plutonium-239 (>90% Pu-239), and its preparation depended on the operation of special nuclear reactors built for the purpose. ![]() It was released over Hiroshima, Japan's seventh largest city, on 6 August 1945. it was equivalent to 16,000 tonnes of TNT). About 64 kilograms of highly-enriched uranium was used in the bomb which had a 16 kiloton yield ( i.e. As UF 6, there is about a one percent difference in mass between the molecules, and this enables concentration of the less common isotope. This was prepared by diffusion enrichment techniques using the very small differences in mass of the two main isotopes: U-235 (originally 0.7% in the uranium) and U-238, the majority. The Hiroshima bomb was made from highly-enriched uranium-235. Several factors suggest that nuclear power has a much larger role to play in supplying the world's future energy needs, and this is supported by every reputable projection. Today, as the main nuclear arsenals are being dismantled and a comprehensive test ban treaty is in sight, commercial nuclear power provides a significant portion of the world's electricity. Nowhere is the transition from weapons of destruction to power for good better displayed than Hiroshima and Nagasaki in Japan which have come to depend substantially on electricity from nuclear energy. In the following years several governments joined the arms race, while internationally, efforts were focused on constraining the threat of nuclear weapons proliferation.įrom the 1950s the power of the atom was harnessed increasingly for peaceful uses, notably electricity generation and medicine. The immense and previously unimaginable power of the atom had been demonstrated. These brought the long Second World War to a sudden end. Two atomic bombs made by the allied powers (USA and UK) from uranium-235 and plutonium-239 were dropped on Hiroshima and Nagasaki respectively early in August 1945. Hiroshima, Nagasaki, and Subsequent Weapons Testing ![]() |
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